Brazing-titanium

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Brazing-titanium is readily performed in a furnace either in vacuum or in a dry argon atmosphere with dew point lower than -55 0C.

Titanium is one of the reactive metals, so called because they react with oxygen to form an adherent and stable oxide. The formation of layers of titanium oxide gives to this metal and to its alloys exceptional corrosion resistance.


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This quality and its specific property of high strength to weight ratio at intermediate temperatures make titanium alloys invaluable for those applications that best exploit the unique capabilities of these materials.

Titanium oxide must be removed by mechanical or chemical means just before brazing otherwise it would hinder wetting if left in place.

An Article on Filler Metal for Brazing-titanium Alloys was published (4) in Issue 46 of Practical Welding Letter for June 2007.
Click on PWL#046 to read it.
Unfortunately the two first references given there are no longer available online.

A short introduction to the different types of Titanium alloys as described by their main phase in the microstructure is given in the above article and also in our page on Titanium Welding.

The influence of alloying elements on Titanium microstructure is outlined in PWL#022.

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Filler Metals

Heat treatments of titanium alloys are established by taking into account the temperatures at which phase transformations occur. Brazing-titanium should be performed at temperatures that do not compromise the mechanical properties expected in the base metal.

Therefore the Brazing-titanium filler alloys should be selected so that their brazing temperature is within the recommended range for heat treatment of the alloys to be brazed.

Titanium commercially pure and alpha alloys should be brazed below the beta transus temperature (that at which the phase changes from alpha to beta), otherwise a coarse grain microstructure could develop with impaired ductility.

The suitability of selected filler metal for Brazing-titanium should be verified by testing to make sure that design requirements for strength and ductility are met after brazing and that there is no danger of galvanic corrosion from the brazing alloy in the actual service.

The following Table shows a few of the most common filler alloys used for Brazing-titanium. It should be noted that many more proprietary alloys are commercially available, and that a few other that were used for academic study may not be readily found in the market.

Table
Brazing Filler Metals for Titanium Alloys
NameTemperature C/F
CompositionSolidusLiquidus
Ag-5Al780/1436810/1490
Ti-20Zr-20Cu-20Ni842/1548848/1558
Ti-15Ni-15Cu830/1526850/1562
Ag-26.7Cu-4.5Ti830/1526850/1562
Ag-9Pd-9Ga845/1553880/1616
Ti-15Cu-15Ni902/1656932/1710
Ag-21.3Cu-24.7Pd900/1652950/1742

Filler metals are available as powders and as foil, sometimes maid by compacting amorphous powders obtained by rapid solidification. The main suppliers advertise their availability for advising on filler metal selection and corrosion resistance.

Resources

1. - Articles:

Brazing Titanium for Structural and Vehicle Applications
Welding Journal, September 2007, pp. 41-46, K.J. Doherty, J.R. Tice,...

State-of-the-Art of Titanium-Based Brazing Filler Metals
Welding Journal, October 2003, pp. 36-43, A. Shapiro and A. Rabinkin

Experiments in Vacuum Brazing of Titanium
http://www.defensetechbriefs.com/content/view/1187/34/

EB Brazing of Ti for Construction in Space
NASA Goddard.

2. - Information from Commercial Sources:

Products and Services (Including a list of trade name of Brazing-titanium Filler Metals)
http://www.titanium-brazing.com/products.html#3

Soldering and brazing-titanium and titanium alloys
ThyssenKrupp Titanium.

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